Rare-Earth Clocks, Sm-Nd and Lu-Hf Dating Models 2: Radioactive Dating, Part 6
by Vernon R. Cupps, Ph.D. | Mar. 31, 2015
This series has summarized radioisotope dating models, their assumptions, and how those assumptions mistakenly lead to a “deep time” picture of our universe.1 Secularist scientists want us to accept their circular arguments and improbable assumptions as scientific fact, despite the fact these same scientists often push aside the scientific method itself.
Using the various types of radioisotope decay as clocks does not produce consistent results, nor are those results verifiable by observational evidence. If these methods do not properly date rocks of known ages—some less than a century old—how can we trust them to date rocks of unknown ages?
Last month we discussed dating methods using rare-earth elements (REEs), a group of seventeen metallic elements—i.e., the lanthanides plus scandium (Sc) and yttrium (Y).
The 147Sm-143Nd model has a problem the previous models we have discussed do not have—i.e., 143Nd is only observationally stable; it is theoretically predicted to undergo alpha (α) decay to 139Ce. Furthermore, the index isotope 144Nd alpha decays to 140Ce with a half-life of approximately (2.29± 0.16) × 1015 yrs.
This introduces a time-dependent concentration into a time-independent linear equation. Since both the daughter and index isotopes vary in time, establishing an initial daughter concentration (via the isochron method) becomes problematic because the y-intercept of the linear plot cannot be assumed to be the primordial ratio of
Geochronologists solve this problem by using “stony meteorites” to establish a primordial isotope ratio for 143Nd to 144Nd and an estimated age of (4.58±0.05) × 109 yrs using the Moama meteorite as a reference standard.2 This method assumes that the terrestrial Nd has evolved in a uniform reservoir whose Sm/Nd ratio is equal to that of a chrondritic meteorite that is further thought to be similar in composition to the current photosphere of the sun minus the volatile elements. Hence, the logic used to estimate the initial value of the daughter isotope concentration springs from the evolutionary models for solar system formation and is, again, quite circular in its essence.
The inhomogeneous distribution of Lu and Hf in granitic rocks and their sensitivity to alteration during metamorphism create reproducibility problems for the Lu-Hf model. The initial or primordial ratio of
must be determined from other dating methods. Even then, the scatter of the data points for the isochron is usually significant, perhaps hinting that the linear plot more closely models a mixing line than an isochron.
Rare-earth dating is plagued by the same questionable four assumptions as the K-Ar, Ar-Ar, and Rb-Sr dating methods,3 and the rocks they supposedly date continue to exhibit behavior that is just as consistent with a mixing line as an isochron line. Half-lives, which figure prominently in date calculations for the REEs, have a high degree of uncertainty, and the methods for measuring the primordial concentration ratios exhibit circular reasoning.
Another assumption that is seldom mentioned is the issue of continuing cosmogenic production of both parent and daughter isotopes in all these aforementioned dating methods. For example, 142Nd is continually produced via the alpha decay of 150Gd, and it in turn continually produces 143Nd via neutron capture reactions from solar radiation. Since 147Sm decay produces only tiny amounts of 143Nd, even small amounts introduced via a process like neutron capture will seriously skew the dates estimated with the 147Sm-143Nd method. All these factors cast significant doubt on the accuracy and reliability of these methods for dating rock formations.
Four geologists, writing in the periodical Geology, had this to say about isochron ages:
The determination of accurate and precise isochron ages for igneous rocks requires that the initial isotope ratios of the analyzed minerals are identical at the time of eruption or emplacement. Studies of young volcanic rocks at the mineral scale have shown this assumption to be invalid in many instances. Variations in initial isotope ratios can result in erroneous or imprecise ages.4
Samuel Bowring and Todd Housh stated in the periodical Science concerning discordant Nd-Sm isochron model values:
It is possible to produce linear arrays on isotope correlation diagrams (even statistically significant ones) that do not have any age significance and are best interpreted as mixing lines. The half-life of 147Sm is so long that even for geologically significant periods of time (hundreds of millions of years) little change occurs in the Nd isotope composition of rocks; thus, a number of rocks that start with slightly different initial ratios and Sm/Nd may produce linear arrays on an isotope correlation diagram with no age significance.5
So what else do the observations say about these REE dating methods? Two isochrons from Grand Canyon’s Bass Rapid’s diabase sill and contact hornfels are discordant by a factor of 2—the diabase mineral isochron giving an age of 1376±140 Ma and the granophyre + hornfels isochron giving an age of 676 ± 280 Ma.6 Which one is correct?
The Mt. Ngauruhoe andesite, which is no older than 65 years, yielded a whole-rock Sm-Nd isochron age of 197 ± 160 million years.7
Basalt from the Uinkaret Plateau in the western Grand Canyon, Arizona, yielded a Sm-Nd isochron model age of 916 ± 570 million years, yet its accepted conventional age is < 1.16 ± 0.18 million years.8
Whole-rock samples from the Somerset Dam layered mafic9 intrusion near Brisbane, Australia, yielded ages for the rock formation from 2,923 to 442 million years. This led the author of a report on the samples, Andrew Snelling, to conclude “and thus its present radioisotopic ratios do not provide its true age by the conventional radioisotope dating techniques.”10
Finally, the measured isochron ages of amphibolite rock from southeast India gave an age of 481 million years using the Rb-Sr method but an age of 824 million years using the Sm-Nd method.11 The researchers explained away the obvious disagreement by claiming the older age was the time at which the rocks underwent metamorphism while the younger age resulted from a later heating of the rocks. How do they know this time sequence? Can they time travel? They are using unknowns to explain unknowns. This is blind faith wrapped in a philosophical premise, not science.
Speculation, conjecture, and reasonable hypotheses all have their place in the scientific process, but they are not scientific fact and should never be presented as such. The secularist will tell us that believing the biblical account of creation is not science, even though the preponderance of the observational evidence points to the truth of the Genesis record. Unfortunately for them, secularists’ worldview of a matter, energy, random-chance universe (naturalism) is also a matter of belief, not science. Do we believe God, whose Word has stood the test of time, or do we believe self-appointed experts who have a long history of mistaken ideas and bankrupt philosophies?
Click here to read Part 7.
- Cupps, V. R. 2014. Clocks in Rocks? Radioactive Dating, Part 1. Acts & Facts. 43 (10): 8-11; Cupps, V. R. 2014. The Iconic Isochron: Radioactive Dating, Part 2. Acts & Facts. 43 (11): 10-13; Cupps, V. R. 2014. The Noble Clock: Radioactive Dating, Part 3. Acts & Facts. 43 (12): 10-13; Cupps, V. R. 2015. Alkali Metal Dating, Rb-Sr Dating Model: Radioactive Dating, Part 4. Acts & Facts. 44 (2): 10-13; Cupps, V. R. 2015. Rare-Earth Clocks, Sm-Nd and Lu-Hf Dating Models: Radioactive Dating, Part 5. Acts & Facts. 44 (3): 10-11.
- Hamet, J., et al. 1978. Origin and history of the adcumulate eucrite, Moama as inferred from REE abundances, Sm-Nd and U-Pb systematics. In Proceedings of the 9th Lunar and Planetary Science Conference. New York: Pergamon Press, 1115-1136.
- Cupps, Clocks in Rocks?, 10.
- Davidson, J., et al. 2005. Mineral isochrons and isotopic fingerprinting: Pitfalls and promises. Geology. 33 (1): 29-32.
- Bowring, S. A. and T. Housh. 1996. Response: Sm-Nd Isotopic Data and Earth’s Evolution. Science. 273 (5283): 1878-1879.
- Snelling, A. A. 2005. Isochron Discordances and the Role of Inheritance and Mixing of Radioisotopes in the Mantle and Crust. In Radioisotopes and the Age of the Earth: Results of a Young-Earth Creationist Research Initiative. Vardiman, L., A. A. Snelling, and E. F. Chaffin, eds. El Cajon, CA: Institute for Creation Research, and Chino Valley, AZ: Creation Research Society, 451.
- Snelling, A. A. 2003. The relevance of Rb-Sr, Sm-Nd, and Pb-Pb Isotope Systematics to Elucidation of the Genesis and History of Recent Andesite Flows at Mt. Ngauruhoe, New Zealand, and the Implications for Radioisotopic Dating. In Proceedings of the Fifth International Conference on Creationism. Ivey, Jr., R. L., ed. Pittsburgh, PA: Creation Science Fellowship, 285-303.
- Morris, J. 2011. The Young Earth. Green Forest, AR: Master Books, 57.
- Mafic is an adjective used to describe silicate minerals or rocks that are rich in magnesium and iron. Common mafic minerals include olivine, pyroxene, amphibole, and biotite.
- Snelling, A. A. Whole-Rock K-Ar Model and Isochron, and Rb-Sr, Sm-Nd, and Pb-Pb Isochron, “Dating” of the Somerset Dam Layered Mafic Intrusion, Australia, Proceedings of the Fifth International Conference on Creationism, 305-324.
- Okudaira, T., et al. 2001. Sm-Nd and Rb-Sr dating of amphibolite from the Nellore-Khammam schist belt, S.E. India: constraints on the collision of the Eastern Ghats terrane and Dharwar-Bastarcraton. Geological Magazine. 138 (4): 495-498.
* Dr. Cupps is Research Associate at the Institute for Creation Research and received his Ph.D. in nuclear physics from Indiana University-Bloomington.
Rare-Earth Clocks, Sm-Nd and Lu-Hf Dating Models: Radioactive Dating, Part 5
Past articles in this series have attempted to establish a foundation for understanding the radioisotope dating models or hypotheses, their assumptions, and how those assumptions lead to a “deep time” picture of our universe. Secularists would have us accept their convoluted, circular arguments as scientific fact simply because the majority of people in the academic community embrace them. More...
Alkali Metal Dating, Rb-Sr Dating Model: Radioactive Dating, Part 4
Using rubidium (Rb) decay as a clock to date minerals was first suggested by Otto Hahn and Ernst Walling in 1938. Five years later, Hahn performed the first age determination using this method. How reliable is it as a means to date geological materials? More...
Ice Cores, Seafloor Sediments, and the Age of the Earth, Part 3
Although creation scientists reject the millions of years that secular scientists have assigned to the seafloor sediments, they do agree that their deposition has been slow and gradual for at least the last few thousand years. But even a few thousand years of slow deposition could only account for a tiny fraction of the total sediments on the ocean floor. How, then, can creation scientists explain the great thickness of these sediments? More...
The Noble Clock: Radioactive Dating, Part 3
Radioactive dating methods—many of which are quite elaborate—have numerous physical condition requirements that cannot realistically remain unaffected over millions and perhaps billions of years. Since the potassium-argon dating methods clearly appear to be unreliable, why should any rational person trust them to provide accurate dates for rocks? More...
- The Iconic Isochron: Radioactive Dating, Part 2
- Clocks in Rocks? Radioactive Dating, Part 1
- Darwin vs. Genetics: Surprises and Snags in the Science of Common Ancestry
- Hijacking the Scientific Method
- Ice Cores, Seafloor Sediments, and the Age of the Earth, Part 2
- Ice Cores, Seafloor Sediments, and the Age of the Earth, Part 1
- The Solar System: Asteroids and Comets
- The Solar System: Pluto
- The Solar System: Neptune
- The Solar System: Uranus
- The Solar System: Saturn
- The Solar System: Jupiter
- The Solar System: Mars
- The Solar System: Earth and Moon